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The Electrochemical Automobile!

oThe electric automobile has been around nearly as long as the internal combustion powered one, according to "Automotive Industries". Today's interest in the  "EV"  or  Electrochemical Vehicle  is prompting research into three electrochemical areas: batteries, fuel cells, and supercapacitors. All three are important for a successful EV.

oThe ACS reported on a Nov 2003 Congress & Business briefing on The Hydrogen Economy. GM, Shell, and Chevron were represented!

oFree New Car Quote if you want check out a new EV:  Toyota Prius or Honda Insite or Civic Hybrid

oCheck Bob's Bookshelf for books on EVs and Fuel Cells.

oHowStuffWorks.com has a resource on Fuel Cells

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The earliest EV's were battery powered, as were the first of the recent crop of EV's ( the GM EV-1). However, the (still) limited range of a solely battery powered EV limits their ability to replace the internal combustion powered car. And there is the question of recharging.

Fuel cells appear to make an attractive alternative to batteries. Hydrogen gas (stored or generated on-board) is combined with oxygen from the air to produce water as the only product. The Greenhouse gas, carbon dioxide, and the smog producing nitrogen oxides and ozone would not be produced as they are in the IC engine. The promise is of a true zero-emission-vehicle (ZEV). The DaimlerChrysler NECAR-4 is in this category and stores liquid hydrogen (at a temperature below -422°F) on-board. An alternative is to generate the hydrogen on-board from methanol in a 'reformer'. Although this was used in the NECAR-3, the reformer produces carbon dioxide as well as hydrogen and adds complexity, weight and expense. However, methanol can be easily stored and dispensed just as gasoline is today.

Even internal-combustion / electric hybrids (such as today's Toyota Prius, Honda Insite, and the new Civic Hybrid) owe something to electrochemical science. Unlike the diesel-electric locomotive [where weight is an advantage and adds to the traction and pulling capacity], low weight is a concern in the automobile. No advantage would be gained if the IC ( Internal Combustion ) engine was sized to provide all the power during peak demand times. Batteries can be used to supplement the IC generated electricity for peak power consumption times (such as drag races from a red light or entering an Interstate.) Regenerative braking  can also improve a EV's efficiency by turning the electric motor into a generator during braking.  Rather than producing heat and brake-pad dust, the kinetic energy of motion is converted into electrical energy and stored in the battery. 

Supercapacitors also play a significant role in the EV. Because they can be efficiently charged rapidly, they make excellent candidates for storing the energy from regenerative braking. They are used in the Honda's FCX V3 fuel cell EV for regenerative braking.

I'm not the only one who associates the EV with electrochemistry!  See Penn State's "Electrochemical Engine Center" website.

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